Dimethyl(3-oxo-3-phenylpropyl)azanium tetrachloridoferrate(III)
نویسنده
چکیده
In the title mol-ecular salt, (C(11)H(16)NO)[FeCl(4)], an intra-molecular N-H⋯O hydrogen bond in the cation generates an S(6) loop and the conformation of the C(=O)-C-C-N chain is gauche [torsion angle = 57.0 (6)°]. The anion is a near-regular tetra-hedron [range of Cl-Fe-Cl angles = 107.93 (8)-112.13 (10)°]. There are no directional inter-ionic bonds in the crystal.
منابع مشابه
1,3-Dimethyl-1H-1,2,3-benzotriazol-3-ium tetrachloridoferrate(III)
The asymmetric unit of the title salt, (C8H10N3)[FeCl4], contains one 1,3-dimethyl-1H-1,2,3-benzotriazol-3-ium cation and one tetra-chloridoferrate anion. The Fe(III) atom in the anion is tetra-hedrally coordinated by four Cl atoms. In the crystal, inter-actions are observed between the Cl atoms and the triazolium ring [Cl⋯centroid distances = 3.587 (3) and 3.866 (3) Å].
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